Inorganica Chimica Acta
Volume 198-200
Main Index
Pages 1-909 (August-October 1992)
Have adenosine 5′-triphosphate ATP
4−
and related purine-nucleotides played a role in early evolution? ATP, its own ‘enzyme’ in metal ion facilitated hydrolysis!
Pages 1-11
Helmut Sigel
Crystallographic disorder in [M
2
X
8
]
n
−
, M
2
X
4
L
4
and related compounds: chemical and theoretical implications
Pages 13-22
F. Albert Cotton, Judith L. Eglin
The preparation of new manganese(II) isocyanide complexes, MnI
2
(CNBu
t
)
n
(
n
=1, 1.5, 2) and the mixed isocyanide/tertiary-phosphine complex MnI
2
(PPh
3
)(CNBu
t
)
2
. The isolation and X-ray crystallographic characterisation of the Mn
I
/Mn
II
mixed-valence isomeric complexes [Mn(CNBu
t
)
6
][MnI
3
(PPh
3
)] and [Mn(CNBu
t
)
5
(PPh
3
)][MnI
3
(CNBu
t
)]
Pages 23-30
Stephen M. Godfrey, Qing Li Guang, Charles A. McAuliffe, Peter T. Ndifon, Robin G. Pritchard
Dioxygen uptake and transfer by Co(III), Rh(III) and Ir(III) catecholate complexes
Pages 31-56
Pierluigi Barbaro, Claudio Bianchini, Klaus Linn, Carlo Mealli, Andrea Meli, Francesco Vizza, Franco Laschi, Piero Zanello
α- versus β-hydrogen elimination in the formation of propene from an osmacyclobutane
Pages 57-61
Wolfgang Fischer, Robert T. Hembre, Daniel R. Sidler, Jack R. Norton
Oxygen atom transfer in the reaction between hexakis(dimethyl-tert-butylsiloxy)ditungsten and nitric oxide. A remarkable difference in the reactivity of the tungsten-tungsten triple bond as a function of the attendant ligands: Bu
t
O versus Bu
t
Me
2
SiO
Pages 63-77
Malcolm H. Chisholm, Cindy M. Cook, Kirsten Folting, William E. Streib
Synthesis and antitumor activity of water-soluble 2-benzyl-1,2-diaminobutane-α-oxycarboxylatoplatinum(II) complexes
Pages 79-84
Henri Brunner, Friedrich Maiterth, Barbara Treittinger
Ni
IV
cubanes: synthesis and characterization of the [Ni
4
Se
4
(Se
3
)
5
(Se
4
)]
4−
and [Ni
4
Te
4
(Te
2
)
2
(Te
3
)
4
]
4−
anions
Pages 85-93
Jonathan M. McConnachie, Mohammad A. Ansari, James A. Ibers
Structural investigations of the hexavanadium core {V
6
O
19
} in ‘oxidized’, mixed valence and ‘reduced’ clusters of the type [V
V
6−
n
V
IV
n
O
13−
n
(OH)
n
{(OCH
2
)
3
CR}
2
]
2−
,
n
=0, 3 and 6
Pages 95-110
Chen Qin, Jon Zubieta
An investigation of the reaction of [Rh
2
(COMe)
2
(CO)
2
I
6
]
2−
with some tertiary phosphines, and PPh(OMe)
2
, and the X-ray structure of [Rh(COMe)I
2
(Ph
2
PCH
2
PPh
2
)]
Pages 111-118
Harry Adams, Neil A. Bailey, Brian E. Mann, Christopher P. Manuel
One- and two-dimensional rare earth-copper molecular materials
Pages 119-131
Olivier Guillou, Olivier Kahn, Robert L. Oushoorn, Kamal Boubekeur, Patrick Batail
On the structures, stabilities and fragmentation patterns of carbon clusters including Buckminsterfullerene
Pages 133-138
Juan J. Novoa, Whangbo Myung-Hwan, Jack M. Williams
Synthesis and crystal structure of a molybdenum carbonyl complex, Mo(CO)
4
[
cyclo
(Ph
6
P
3
As
3
)], with scrambled phosphorus/arsenic identities obtained from a perfectly alternating phosphorus-arsenic heterocycle, 1,3,5-tris(phenylphospha)-2,4,6-tris(phenylarsa)cyclohexane, [
cyclo
(Ph
6
P
3
As
3
)]
Pages 139-143
Arnold L. Rheingold, Frederick P. Arnold
Electronic absorption spectra of M(II)(Met121X) azurins (M=Co, Ni, Cu; X=Leu, Gly, Asp, Glu): charge-transfer energies and reduction potentials
Pages 145-148
Angel J. Di Bilio, Thomas K. Chang, Bo G. Malmström, Harry B. Gray, B. Göran Karlsson, Margareta Nordling, Torbjörn Pascher, Lennart G. Lundberg
The synthesis of
endo
-3-diphenylphosphino-(1
R
)-(+)-camphor (L) and some of its complexes with palladium(II), platinum(II) and rhodium(I); crystal structures of L and
cis
-[PdCl
2
L
2
]
Pages 149-158
Sarath D. Perera, Bernard L. Shaw, Mark Thornton-Pett, Jonathan D. Vessey
Monocomplex formation and dissociation of some first row divalent transition metal ions with 2-chloro-1,10-phenanthroline by the high-pressure stopped-flow technique
Pages 159-164
Gábor Laurenczy, Pascal Bugnon, André E. Merbach
Synthesis and structures of novel types of heteronuclear Pt---M (M=Ag, Sn or Pb) neutral or anionic organometallic complexes
Pages 165-177
R. Usón, J. Forniés
Coordination chemistry of nitriles and cyanamide at electron-rich metal centres
Pages 179-186
Armando J.L. Pombeiro
Mechanistic information on the reaction of model palladium(II) complexes with purine nucleosides and 5′-nucleotides in reference to the antitumor activity of related platinum complexes
Pages 187-192
M. Shoukry, H. Hohmann, R. van Eldik
Activation of dithioformate by iron complexes: insertion of alkynes into the coordinated C---S bond. X-ray structures of
(SMe)H](CO)(PMe
3
)
2
and
H---CH(SMe)](CO)(PMe
3
)
2
Pages 193-201
Dilip V. Khasnis, Nadine Pirio, Daniel Touchard, Loïc Toupet, Pierre H. Dixneuf
Subvalent Group 14 metal compounds. XIV. The X-ray crystal structures of two monomeric Group 14 metal bisamides, Ge[N(SiMe
3
)
2
]
2
and Sn[
Me
2
]
2
Pages 203-209
Richard W. Chorley, Peter B. Hitchcock, Michael F. Lappert, Wing-Por Leung, Philip P. Power, Marilyn M. Olmstead
The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru
3
(μ
3
-η
3
-CHCHCMe)(CO)
9
and its PPh
3
derivatives
Pages 211-217
K.Mohan Rao, Robert J. Angelici, Victor G. Young Jr.
Kinetics and mechanism of CO ligand substitution in the ring-substituted indenyl rhodium complexes [(η
5
-C
9
R
n
H
7−
n
)Rh(CO)
2
]
Pages 219-231
Ashok K. Kakkar, Nicholas J. Taylor, Todd B. Marder, Jian K. Shen, Noel Hallinan, Fred Basolo
Axial ligand bonding in blue copper proteins
Pages 233-243
Michael D. Lowery, Edward I. Solomon
Mass spectroscopic evidence for the formation of mixed-metal octahedral clusters [Mo
n
W
6−
n
Cl
14
]
2−
Pages 245-248
Hamdallah A. Hodali, Hoying Hung, Duward F. Shriver
Organotin(IV) compounds of 2-thiopyridine. Crystal and molecular structure of dicyclohexyltin(IV) bis(2-pyridylthiolate)
Pages 249-255
Mohammed Bouâlam, Jacqueline Meunier-Piret, Monique Biesemans, Rudolph Willem, Marcel Gielen
Phosphorus-carbon bond cleavage at a di-iron centre: synthesis of μ-phosphidomethyl complexes [Fe
2
(CO)
6
(μ-CH
2
PR
2
)(μ-PR
2
)] from [Fe
2
(CO)
6
(μ-R
2
PCH
2
PR
2
)]
Pages 257-270
Nancy M. Doherty, Graeme Hogarth, Selby A.R. Knox, Kirsty A. Macpherson, Frauke Melchior, David A.V. Morton, A.Guy Orpen
Use of the 2,6-bis[(dimethylamino)methyl]phenyl ligand to form some pentacoordinate derivatives of P(III), As(III), Sb(III) and Bi(III)
Pages 271-274
David A. Atwood, Alan H. Cowley, Jaime Ruiz
Synthesis and NMR structural studies of allyl(polypyrazolylborate)palladium and platinum complexes
Pages 275-282
Kenzo Ohkita, Hideo Kurosawa, Takeya Hasegawa, Tomohide Shirafuji, Isao Ikeda
Synthesis, characterization and reactivity of some mono- and dinuclear chlororuthenium complexes containing chelating ditertiary phosphines (P---P) with P---P:Ru=1
Pages 283-296
Ajey M. Joshi, Ian S. Thorburn, Steven J. Rettig, Brian R. James
The reactivity of spectroscopically detected peroxy complexes of iron porphyrins
Pages 297-307
Alan L. Balch
Beryllocene and related slip-sandwich structures
Pages 309-318
James K. Beattie, Kerry W. Nugent
New trends in polyoxometalate chemistry, toward large polyanions, toward nitrosyl-substituted polyanions
Pages 319-336
Y. Jeannin, G. Hervé, A. Proust
Preparation and reactions of some organosilicon cyanates
Pages 337-344
Colin Eaborn, Yousef Y. El-Kaddar, Paul D. Lickiss
Application of the ligand polyhedral model to dicobalt octacarbonyl
Pages 345-349
Brian F.G. Johnson, Emilio Parisini
Transition-metal complexes with sulfur ligands. Part LXXXIV. CH
3
complexes with [NiS] fragments as models for CO dehydrogenase. Synthesis and properties of [Ni(‘MeS
2
’)
2
] and (NMe
4
)[Ni(CH
3
)(‘MeS
2
’)
2
] (‘MeS
2
’
−
=
o
-(methylthio)thiophenolate(1−))
Pages 351-357
Dieter Sellmann, Helmut Schillinger, Falk Knoch, Matthias Moll
A classification scheme for homogeneous metal catalyzed oxidations by O
2
Pages 359-367
Russell S. Drago, Robert H. Beer
Anionic dicarbollyl complexes of germanium(II) and tin(II) — missing links in a series of π-complexes with Group 14 elements as central atoms
Pages 369-375
Peter Jutzi, Dirk Wegener, Hans-Georg Stammler, Alexander Karaulov, Michael B. Hursthouse
Synthesis and comparative chemistry of the early-late transition metal heterobimetallacycles CpCp′Ta(CH
2
)
2
Ir(CO)(L) and their main-group element-late transition metal analogues R
2
P(CH
2
)
2
Ir(CO)(L)
Pages 377-392
Michael J. Hostetler, Matthew D. Butts, Robert G. Bergman
Synthesis and characterisation of some hexanuclear heterometallic clusters containing arene ligands; the crystal and molecular structures of RuOs
5
(CO)
15
(η
6
-C
6
H
6
) and RhOs
5
(CO)
15
(η
5
-C
5
Me
5
)
Pages 393-400
Richard K. Henderson, Patricia A. Jackson, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby
Iron(II) thiolates as reversible carbon monoxide carriers
Pages 401-405
Anikó Szakács-Schmidt, József Kreisz, Lászlo Markó, Zsuzsa Nagy-Magos, János Takács
Electron impact (EI) and fast-atom bombardment (FAB) mass spectra of coordination complexes: aggregation processes in the mass spectra of metal derivatives of 1,2,3,4,5-pentakis-(methoxycarbonyl)cyclopentadiene
Pages 407-413
Michael I. Bruce, Michael J. Liddell
Metal complexes of biologically important ligands. Part LXIV. Pentamethylcyclopentadienyl-rhodium(III) complexes with α-amino acid derivatives as bridging ligands and with several chiral metal centers: synthesis and structure of [Cp*Rh(μ-
L
-phenylalaninato)]
3
(BF
4
)
3
and [Cp*Rh(μ-NHCOCH
2
NCO
2
CH
2
Ph)]
2
Pages 415-420
Roland Krämer, Kurt Polborn, Christian Robl, Wolfgang Beck
New synthetic, selective, high-affinity ligands for effective trivalent metal ion binding and transport
Pages 421-428
Ramunas J. Motekaitis, Yizhen Sun, Arthur E. Martell
Synthesis and characterization of some new complexes of the Vaska-type
trans
-[IrX(CO)L
2
] (X=Cl or I; L=phosphite, phosphinite or phosphonite) and the direction of dihydrogen addition to these species
Pages 429-435
Luo Xiao-Liang, Demetrius Michos, Robert H. Crabtree, Michael B. Hall
Ruthenium(II) complexes of a 2,2′-biphosphinine
Pages 437-441
Duncan Carmichael, Pascal Le Floch, Louis Ricard, François Mathey
Synthesis and characterization of compounds with boron-boron double bonds
Pages 443-447
Philip P. Power
Tris(1,2-ethanediamine) complexes of osmium(IV), osmium(III) and osmium(II): oxidative dehydrogenation reactions
Pages 449-460
Peter A. Lay, Alan M. Sargeson
Synthesis and reactivity of digermylplatinum(II) complexes Me
2
tL
2
(
n
=0, 1, 2)
Pages 461-467
J. Barrau, G. Rima, V. Cassano, J. Satgé
New trinuclear and hexanuclear ruthenium clusters derived from the reaction of [Ru
3
(CO)
12
] with phenylphosphine or cyclohexylphosphine
Pages 469-481
Antony J. Deeming, Simon Doherty, Nicholas I. Powell
NMR is a unique and necessary step in the investigation of iron sulfur proteins: the HiPIP from
R. gelatinosus
as an example
Pages 483-491
Ivano Bertini, Francesco Capozzi, Claudio Luchinat, Mario Piccioli, Margarita Vicens Oliver
Molecular architecture of copper(I) thiometallate complexes. Example of a cubane with an extra face, (NPr
4
)
3
[MS
4
Cu
4
Cl
5
] M=Mo, W)
Pages 493-505
Yves Jeannin, Francis Sécheresse, Sylvain Bernès, Francis Robert
Hexanuclear polypyridine complexes containing different metals, bridging ligands and/or terminal ligands. Absorption spectra, electrochemical oxidation, luminescence properties and intercomponent energy transfer
Pages 507-512
Gianfranco Denti, Scolastica Serroni, Sebastiano Campagna, Vittorio Ricevuto, Alberto Juris, Mauro Ciano, Vincenzo Balzani
Octahedro octahedra and tetrahedra. II. Tetra- to heptanuclear carbonyl(cyano)chromato, -molybdato and -tungstato complexes of 3d metals
Pages 513-526
Marcus Fritz, Dirk Rieger, Eberhard Bär, Gerhard Beck, Joachim Fuchs, Gerhard Holzmann, Wolf P. Fehlhammer
Highly fluorinated tetrazanes and other polynitrogen compounds
Pages 527-531
Ghulam Sarwar, Nimesh R. Patel, Zheng Yuan Yang, Earnest Obed John, Robert L. Kirchmeier, Jean'ne M. Shreeve
Manganese(II)cyclopentadienide and cyclopentadienylmanganese(biphenyl) as starting materials for the synthesis of carbonyl free organomanganese complexes
Pages 533-541
Klaus Jonas, Claus-Christian Häselhoff, Richard Goddard, Carl Krüger
Protonation of cobalt tetraneopentoxyphthalocyanine as a function of oxidation state
Pages 543-555
Paul A. Bernstein, A.B.P. Lever
Metal insertion into a CH bond as a route to the heterobimetallic μ-methylidene complex C
5
H
5
(CO)
2
Re(μ-CH
2
)Pt(PPh
3
)
2
Pages 557-564
Charles P. Casey, Yan Wang, Lori M. Petrovich, Todd L. Underiner, Paulette N. Hazin, John M. Desper
Synthesis and reactivity of molybdenum-sulfur cubes
Pages 565-575
C.L. Coyle, K.A. Eriksen, S. Farina, J. Francis, Y. Gea, M.A. Greaney, P.J. Guzi, T.R. Halbert, H.H. Murray, E.I. Stiefel
Acyclic mononuclear and macrocyclic dinuclear silver(I) complexes of Schiff base ligands derived from
N
,
N
-bis(2-aminoalkyl)-2-phenylethylamines
Pages 577-581
David.E. Fenton, Paul C. Hellier
Preparation and spectroscopic characterization of (η
6
-arene)ruthenium(II) trifluoromethylsulfonates and of dinuclear di-μ- and tri-μ-hydrido (η
6
-arene)ruthenium(II) complexes. Homogeneous hydrogenation of cyclohexene and 1-hexene catalysed by various (η
6
-arene)ruthenium(II) complexes
Pages 583-592
Martin A. Bennett, James P. Ennett
Synthesis of complexes with molybdenum-platinum bonds from the alkylidyne(carborane)molybdenum reagent [NEt
4
][Mo(
CC
6
H
4
Me-4)(CO)
2
(η
5
-C
2
B
9
H
9
Me
2
)]
Pages 593-600
John C. Jeffery, Mark D. Mortimer, F.Gordon A. Stone
Nucleophilic addition of chromium carbene anions to the coordinated olefin in [Cp(CO)
2
Fe(η
2
-olefin)]
+
complexes and to the cyclohexadienyl ligand in [(η
5
-cyclohexadienyl)(CO)
3
Fe]
+
Pages 601-611
Colleen Kelley, Michael R. Terry, Anne W. Kaplan, Gregory L. Geoffroy, Noël Lugan, René Mathieu, Brian S. Haggerty, Arnold L. Rheingold
Magnetochemistry of the tetrahaloferrate(III) ions. 6. Crystal structure and magnetic ordering in [(pyH)
3
Cl][FeCl
4
]
2
Pages 613-621
Roey Shaviv, Carol B. Lowe, Jalal A. Zora, Christer B. Aakeröy, Peter B. Hitchcock, K.R. Seddon, Richard L. Carlin
Procedures for the conversion of μ
2
S→μ
2
O in trinuclear Mo(IV)
3
incomplete cuboidal Mo/S cluster complexes
Pages 623-626
Liu Qiu-Tian, Jiaxi Lu, A. Geoffrey Sykes
Models of the oxidized forms of polyiron oxo proteins: synthetic routes to (μ-oxo)bis(μ-carboxylato)diiron(III) complexes with neutral monodentate and bidentate capping ligands
Pages 627-631
Kingsley L. Taft, Axel Masschelein, Shuncheng Liu, Stephen J. Lippard, Diana Garfinkel-Shweky, Avi Bino
Kinetics and mechanism of oxidative cleavage of the metal-metal bond in [M
2
(CO)
10
]
2−
, M=Cr, Mo and W
Pages 633-638
Julia R. Phillips, William C. Trogler
Heterometallic species containing Cp
2
MH
2
(M=Mo and W) and Cu
+
or Ag
+
are inner sphere redox intermediates
Pages 639-649
Larry F. Rhodes, John C. Huffman, Kenneth G. Caulton
Spectroscopic and electrochemical aspects of copper(II) chelates containing 1,2-diamines and β-ketoenols
Pages 651-661
Chris Tsiamis
Zinc complexes of cyclohexane triamine ligands
Pages 663-669
U. Brand, H. Vahrenkamp
Characterisation of intermediates involved in the
mer
-W(CO)
3
(η
1
-dpm)(η
2
-dpm) to
mer
-[W(CO)
2
(η
2
-dpm)
2
]
2+
(dpm=Ph
2
PCH
2
PPh
2
) oxidation process in acetone by steady-state and fast scan voltammetry at platinum and mercury microelectrodes
Pages 671-677
Alan M. Bond, Ray Colton, Roger S. Hutton
Structures and dynamic features of dinuclear tartratozirconocene complexes
Pages 679-687
Gerhard Erker, Mathias Rump, Carl Krüger, Matthias Nolte
Monoazadienes ruthenium carbonyl chemistry
Pages 689-703
C.J. Elsevier, W.P. Mul, K. Vrieze
Hydridosilicates: a new class of pentacoordinated silicon derivatives with unusual properties
Pages 705-713
R. Corriu, C. Guérin, B. Henner, Q. Wang
Homo- and heterometallic transition-metal complexes containing bis(cyclopentadienyl)methane as ligand
Pages 715-721
Helmut Werner
Metal-stabilized rare tautomers of nucleobases. 4. On the question of adenine tautomerization by a coordinated platinum(II)
Pages 723-732
Bernhard Lippert, Helmut Schöllhorn, Ulf Thewalt
The reaction of disilenes with P
4
and As
4
Pages 733-739
Alan D. Fanta, Robin P. Tan, Nadia M. Comerlato, Matthias Driess, Douglas R. Powell, Robert West
Intermediates of the cyclotrimerization of 2-butyne with a chromium catalyst
Pages 741-748
Günther Wilke, Horst Benn, Richard Goddard, Carl Krüger, Brigitta Pfeil
Weak interactions in metal complexes of amino acids with a phosphorylated side chain. Conversion of aromatic ring stacking to electrostatic bonding by tyrosine phosphorylation
Pages 749-761
Osamu Yamauchi, Akira Odani, Hideki Masuda
New silanediyl (silylene) complexes of ruthenium(0)
Pages 763-769
Hermann Handwerker, Christian Leis, Siegfried Gamper, Christian Zybill
Synthesis and molecular structure of optically active oxazolidine complexes of platinum(II) and palladium(II)
Pages 771-780
A. Albinati, F. Lianza, H. Berger, C. Arz, P.S. Pregosin
Chemical hardness and the electronic chemical potential
Pages 781-786
Ralph G. Pearson
The redox chemistry of the triply bonded compounds Re
2
X
4
(μ-dmpm)
3
(X=Cl or Br; dmpm=Me
2
PCH
2
PMe
2
) and the isolation and characterization of the nitrosyl complex Re
2
Cl
5
(μ-dmpm)
2
(NO)
Pages 787-794
Irene Ara, Richard A. Walton
Strong exchange coupling between the lanthanide ions and the phthalocyaninato ligand radical in bis(phthalocyaninato)lanthanide sandwich compounds
Pages 795-803
Kathleen L. Trojan, Jonathan L. Kendall, Keith D. Kepler, William E. Hatfield
199
Hg NMR investigation on the solution structure of Hg(II) complexes of oligopeptides containing cysteine and histidine residues
Pages 805-811
Hayamitsu Adachi, Norikazu Ueyama, Akira Nakamura
Magnetic and spectral properties of paramagnetic metal-ion polyoxolene radical complexes
Pages 813-822
Andrea Dei, Dante Gatteschi
A Marcus-type model for steric and electronic effects of ligands in atom transfer reactions of metal carbonyl radicals
Pages 823-830
Choi Moon-Gun, Theodore L. Brown
Synthesis and photophysical characterization of highly luminescent complexes of Ru(II) containing 4,4′-di-(
p
-carboxyphenyl)-2,2′-bipyridine
Pages 831-839
K. Kalyanasundaram, Md.K. Nazeeruddin, M. Grätzel, G. Viscardi, P. Savarino, E. Barni
The icosahedron in inorganic chemistry
Pages 841-861
R.Bruce King
Covalent linkage of glucose oxidase to modified basal plane pyrolytic graphite electrodes and the use in the ferrocene-mediated amperometric measurement of glucose
Pages 863-866
Kati di Gleria, H.Allen O. Hill
The use of rigid organic microemulsions to fix liquid solutions for Mössbauer studies
Pages 867-871
Kálmán Burger, Zsuzsanna Nemes-Vetéssy, Attila Vértes, Zoltán Homonnay, Imre Dékány, Hartmut Mehner
The relevance of hydrogen bonding in the mechanism of action of platinum antitumor compounds
Pages 873-881
Jan Reedijk
Synthesis of heterocyclic systems by activation of isocyanide, carbonyl, trifluoromethyl and nitrile ligands in platinum(II) and palladium(II) complexes
Pages 883-897
Umberto Belluco, Rino A. Michelin, Renzo Ros, Roberta Bertani, Giacomo Facchin, Mirto Mozzon, Livio Zanotto
